Silicone defoamer compositions

ABSTRACT

Defoamer compositions contain a) a two-stage hydrosilylation product of one or more M 4   H Q or M 3   H T phenyl  starting materials with a hydrosilylatable composition containing α-methylstyrene, and then with a linear or branched organopolysiloxane bearing at least two hydrosilylatable groups; b) a silicone resin; and c) silica. The defoamers are particularly useful in machine laundering and dishwashing compositions.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The invention pertains to silicone defoamer compositions containingorganopolysiloxane-crosslinked arylalkyl-group-containing T and Q siloxyunits.

2. Description of the Related Art

Many aqueous systems foam excessively under agitation, and are thus inneed of foam control agents to control the amount of foam generated. Theaqueous systems may be of natural or synthetic origin, particularly thelatter. Examples include surfactant-laden emulsions from oil and gasrecovery, and the so-called “black liquor” from the processing ofcellulosic and lignocellulosic fiber-containing materials into paperproducts. Additional examples include, in particular, aqueous washingcompositions for use in laundering and machine dishwashing. While mosthand dishwashing compositions are designed to be high foaming togenerate a perception of high cleaning activity, the generation of foamin clothes washers and machine dishwashers is known to interfere withcleaning ability. Moreover, excessive foaming can impose a much greaterload on the electrical motor driving such devices, to the point ofthermal destruction of the motor. The foam additionally presents thepossibility of overflow and thus water damage to surrounding areas.

To mitigate these undesirable effects, surfactants used in machinelaundering and dishwashing and other fields, have often been of the lowfoaming type. Unfortunately, cleaning efficiency is frequentlycompromised by their use. In addition, other ingredients in detergentformulations, for which there are no low foaming substitutes available,may also produce foam.

Thus, in fields where high cleaning efficiency and/or low foamgeneration is necessary, defoamers have been added to reduce the amountof foam generated and/or to achieve rapid collapse of foam. For thispurpose, a wide variety of materials have been proposed over the decadesas defoamers. Early on, products such as mineral oils, high boilingpetroleum fractions and long-chain alkyl industrial products such astall oil acids and oxo alcohols have been used. Silicone fluids,particularly polydimethylsiloxanes, have also been used. Most of thesematerials continue to be used today. However, in many cases, theirdefoaming activity is too low, or other problems, such as objectionableodor, prevent their use.

Moreover, some defoamers have proven acceptable in some defoamingapplications, but not in others. Black liquor, for example, presents aharsh environment which can cause defoamers to decompose and lose theireffectiveness, while laundry detergent compositions often contain veryhigh levels of surfactants, and highly alkaline substances, which rendermany defoamers ineffective.

WO 03/089108 discloses particulate foam control agents containing 1-30parts by weight of a silicone antifoam, 45-99 parts particulate carrier,2-50 parts of fluorescent whitening agent, and 1-40 parts binder. Thesilicone antifoams are conventional linear or branched siliconesterminated by trimethylsilyl groups, as disclosed in EP-A-578424. Othersilicone antifoams are stated to be disclosed in GB 639673, EP 31532, EP217501, EP 273,448, DE 38 05 661, GB 2,257,709, and EP-A-1,075,864.

U.S. Pat. No. 6,521,587 B1 attests to the long sought need for defoamersin heavy duty detergent formulations, and proposes use of defoamerscontaining chain-pendent alkylphenyl-substituted poly(ethyl,methyl)siloxanes; a water-insoluble hydrocarbonoxy oil such as mineraloil, vegetable oil, or insoluble hydrocarbon alcohols, carboxylic acids,or esters; an organosilicon resin, and a hydrophobic filler, the foamcontrol agent being free of polydimethylsiloxanes or containing lessthan 20 wt. % polydimethylsiloxane based on the weight of thealkylphenyl-substituted organopolysiloxane.

U.S. Pat. No. 8,536,109 B2 discusses the long sought need for efficientdefoamers in liquid detergent formulations for laundering, and proposesa mixture of chain-pendent alkaryl-substituted organopolysiloxanes ofthe same type as in U.S. Pat. No. 6,521,587 B1 together with a silicone“resin” (which non-conventionally also includes linear silicone fluids)as a silicone defoamer, a hydrophobic filler, and a further polyethergroup-containing silicone resin containing both T and Q units.

WO 2013/167430 A1 discloses the continued need for efficient defoamers,and proposes the use of alkylene-linked organopolysiloxanes, fillers,organopolysiloxane resins, and optionally cyclic organopolysiloxanes, inheavily surfactant-loaded detergent formulations. The preparation of thedefoamers starts with the cohydrolysis of vinyl- and hydrido-functionalsilanes, and generates considerable amounts of byproducts.

U.S. Pat. No. 6,521,586 B1 is similar in disclosure to U.S. Pat. No.6,521,587 B1, and discloses similar ingredients, but does not require awater-insoluble non-silicon-containing organic fluids.

U.S. Pat. No. 8,084,566 B2 discloses long lasting defoamers which areproduced by hydrosilylating an Si—H functional organopolysiloxane withan allyl ether-terminated organopolysiloxane, followed by reaction witha diisocyanate to produce urethane-linked composite polyether/siliconecompounds, and which also contain a silicone resin.

U.S. Pat. No. 8,222,303 B2 discloses defoamer compositions containing anorganopolysiloxane defoamer, hydrophilic silica, and apolyethersilicone. The defoamers are particularly useful in defoamingblack liquor.

U.S. Pat. No. 8,461,221 discloses pulverulent antifoam particlescomprising a silicone antifoam absorbed into a porous copolymer of urea,melamine, or a mixture of urea and melamine. The defoamers are said tobe particularly useful in laundry detergent formulations.

There has been a continuing long sought need to provide defoamercompositions where one or more of the principal defoamers are easilysynthesized, which provide high defoaming activity, and whose structurecan be tailored for the particular end use desired.

SUMMARY OF INVENTION

It has now been surprisingly and unexpectedly discovered that efficientand tailorable defoamer compositions can be prepared from a siliconeresin component, a silica component, and a silicone defoamer whichcontains arylalkyl-substituted MQ units and/or arylalkyl-substitutedMT^(phenyl) units linked by Si—C bonds to a linear or branchedorganopolysiloxane.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 discloses in schematic form, one embodiment of a syntheticpathway to produce an inventive silicone defoamer component.

FIG. 2 discloses in schematic form, a second embodiment of a syntheticpathway to produce an inventive silicone defoamer component.

FIG. 3 discloses in schematic form, a third embodiment of a syntheticpathway to produce an inventive silicone defoamer component

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The silicone defoamer is a two-stage hydrosilylation product of an M₁^(H)Q organopolysiloxane or of an M₃ ^(H)T^(phenyl) organopolysiloxanewith a hydrosilylatable hydrocarbon comprising α-methylstyrene in afirst stage, and with a di- or polyalkenyl-functional organopolysiloxanein a second stage.

The M₄ ^(H)Q organopolysiloxanes have the structure [M^(H)O]₄Si where Qis SiO_(4/2) and M^(H) is a monovalent organosilicon group of theformula H—Si(R₂ ¹) where R¹ is an organo group, preferably a C₁₋₁₈ alkylor C₆ or C₁₀ aryl group, the aryl groups optionally substituted by oneor more C₁₋₁₈ alkyl groups, preferably methyl groups. R¹ is preferablyC₁₋₁₈ alkyl, more preferably methyl. M^(H) groups with one methyl andone long chain alkyl group are also preferred. The most preferred M₄^(H)Q compound is tetrakis(dimethylsiloxy)silane, “TDSS.”

The M₃ ^(H)T^(phenyl) starting materials have M^(H) groups as describedabove, attached to a phenyl-substituted SiO_(3/2) group, thus having thestructure [M^(H)-O]₃—Si-Φ where Φ is a phenyl group. Mixtures of M₄^(H)Q and M^(H)T^(phenyl) starting materials may be used.

In the first stage of the reaction, the M₄ ^(H)Q or M₃ ^(H)T^(phenyl),starting materials are reacted with a hydrosilylatable hydrocarboncomprising α-methylstyrene in the presence of a hydrosilylationcatalyst. The M^(H) groups hydrosilylate the α-methylstyrene andoptional further hydrosilylatable higher alkene to substitute the Msiloxy group silicon atoms with an Si—C bonded1-(2-methyl-2-phenyl)ethyl group, which may also be termed an“α-methylphenylethyl” group. It is preferable that at least two M^(H)groups in the M₄ ^(H)Q and/or at least one M^(H) groups in the M₃^(H)T^(phenyl) starting materials silylate α-methylstyrene.

Hydrosilylation catalysts and hydrosilylation reaction conditions arewell known. The reaction typically takes place to the exclusion ofwater, under an inert gas atmosphere, such as a dry nitrogen atmosphere.However, any suitable hydrosilylation conditions, as are well known inthe art, may be used. The reaction may take place neat, or in thepresence of one or more organic solvents, such as toluene, xylene, otheraromatic hydrocarbons, paraffinic hydrocarbons, ketones, ester solventssuch as ethyl acetate, etc. Neat reaction is preferred. If a higheralkene, e.g. a C₆-C₂₀ alkene, preferably an α-alkene is present, it ispresent in a minor portion, <50 mol %, preferably <20 mol % of totalhydrosilylatable compounds. Preferably, no higher alkene is present.

Suitable hydrosilylation catalysts include platinum, rhodium, palladium,ruthenium, and iridium, preferably platinum and rhodium. The metals mayoptionally be fixed to finely divided support materials, such asactivated carbon, metal oxides, such as aluminum oxide or silicondioxide. Preference is given to using platinum and platinum compounds.Particular preference is given to those platinum compounds which aresoluble in polyorganosiloxanes. Soluble platinum compounds that can beused include, for example, the platinum-olefin complexes of the formulae(PtCl₂.olefin)₂ and H(PtCl₃.olefin), preference being given in thiscontext to the use of alkenes having 2 to 8 carbon atoms, such asethylene, propylene, isomers of butene and of octene, or cycloalkaneshaving 5 to 7 carbon atoms, such as cyclopentene, cyclohexene, andcycloheptene. Other soluble platinum catalysts are theplatinum-cyclopropane complex of the formula (PtCl₂.C₃H₆)₂, the reactionproducts of hexachloroplatinic acid with alcohols, ethers, and aldehydesor mixtures thereof, or the reaction product of hexachloroplatinic acidwith methylvinylcyclotetrasiloxane in the presence of sodium bicarbonatein ethanolic solution. Platinum catalysts with phosphorus, sulfur, andamine ligands can be used as well, e.g., (Ph₃P)₂PtCl₂. Particularlypreferred are complexes of platinum with vinylsiloxanes, such assym-divinyltetramethyldisiloxane, and solutions of chloroplatinic acid.

The amount of hydrosilylation catalyst (E) used is governed by thedesired reaction rate and also by economic considerations. Typically,per 100 parts by weight of organopolysiloxanes, 1×10⁻⁵ to 5×10⁻² partsby weight, preferably 1×10⁻⁴ to 1×10⁻², and more particularly 5×10⁻⁴ to5×10⁻³ parts by weight of platinum catalysts, calculated as platinummetal, are used. The platinum catalyst may be added in portions duringthe reaction, especially at the beginning of the second stage.

The mole ratio of α-methylstyrene (and optional higher alkene) toSi-bonded hydrogen in the M₄ ^(H)Q groups is generally at least 1.8:1,more preferably at least 2:1, and preferably not more than 3.2:1, morepreferably not more than 3:1. If a ratio of >3:1 is used, the productmixture will contain some M₄Q units where all four M groups aresubstituted by α-methylphenylethyl groups, and these compounds thus willbe unreactive in the second stage hydrosilylation. The mole ratio ofα-methylstyrene (and optional higher alkene) to Si-bonded hydrogen inthe M₃ ^(H)T^(phenyl) groups is generally at least 0.8:1, morepreferably at least 1:1, and preferably not more than 2.2:1, morepreferably not more than 2:1. If a ratio of >2:1 is used, the productmixture will contain some M₃T^(phenyl) units where all three M groupsare substituted by α-methylphenylethyl groups, and these compounds thuswill be unreactive in the second stage hydrosilylation. The presence ofsuch molecules can be tolerated, but their presence is not preferred.

At mole ratios of less than 2:1 in case of M₄ ^(H)Q, and less than 1:1in case of M₃ ^(H)T^(phenyl), there may be insufficientα-methylphenylethyl groups to produce sufficient defoamer effectiveness.Moreover, the higher number of residual, unreacted silicon-bondedhydrogen groups may increase any or all of the viscosity, the molecularweight, and the degree of crosslinking of the final product. Forexample, if the average number of residual Si—H groups is 1, and thehydrosilylatable organopolysiloxane to be used in the second stage has afunctionality of 2, an A-B-A structure of relatively low molecularweight will be formed. If, under the same circumstances, the averagenumber of residual Si—H groups is 1 and the functionality of thehydrosilylatable organopolysiloxane is 3, again, a relatively lowmolecular weight branched polymer of A-B(A)-A structure will be formed.

If, however, both the first stage product and the hydrosilylatableorganopolysiloxane have functionalities of close to 2, a linear buthigher molecular weight A-(B-A)_(n)-A structure will be formed. If thechain length n is too large, the product may no longer be fluid. If thefunctionalities average significantly higher than 2, crosslinked solidelastomers, which are not within the scope of the invention, may beformed. Thus, the number of α-methylphenylethyl groups on average ispreferably between 2 and 3 in case of M₄ ^(H)Q, and between 1 and 2 incase of M₃ ^(H)T^(phenyl), and thus the preferred residual Si—Hfunctionality is between 1 and 2.

In the second stage of the reaction, the first stage reaction product isused to hydrosilylate a hydrosilylatable organopolysiloxane. Again, thehydrosilylation catalysts and reaction conditions are conventional.

The hydrosilylatable organopolysiloxane is a linear or branchedorganopolysiloxane bearing aliphatically unsaturated groups amendable tohydrosilylation. Such groups are well known, and include, for example,alkenyl groups, preferably w-alkenyl groups. Non-limiting examplesinclude vinyl, allyl, 2-propenyl, isopropenyl, 5-hexenyl, norbornadenyl,cyclohexenyl, ethynyl, and 3-butynyl. Vinyl groups are the preferredhydrosilylatable groups.

The hydrosilylatable groups may be terminal groups or chain-pendentgroups, or both. At least two hydrosilylatable groups are present onaverage, and preferably no more, on average, than 10 such groups arepresent, more preferably no more than 7.

The organo groups of the hydrosilylatable organopolysiloxane (other thanthe hydrosilylatable groups) are all those organo groups useful inconventional organopolysiloxanes which are not hydrosilylatable.Examples of such groups are alkyl groups such as C₁₋₁₈ alkyl groups,preferably C₁₋₄ alkyl groups, and preferably the methyl group; arylgroups such as phenyl and naphthyl and substituted aryl groups such asC₁₋₁₈ alkyl-substituted phenyl groups and chlorophenyl groups; andaralkyl groups such as phenylethyl and α-methylphenylethyl. Methylgroups and phenyl groups are preferred, and mixtures of methyl andphenyl groups are also preferred.

The preferred hydrosilylatable organopolysiloxanes are thusα,ω-divinylpolydimethylsiloxanes, α,ω-divinylpolydimethylsiloxanes alsobearing further, chain-pendent hydrosilylatable groups; andpoly(dimethyl)(methylvinyl)siloxanes, where all hydrosilylatable groupsare chain-pendent. More than one type and/or functionality ofhydrosilylatable organopolysiloxane can be used. Mono-functionalhydrosilylatable organopolysiloxanes may also be present in addition tothose having functionalities of two or higher, but this is notpreferred. If present, these should contain less than 40 mol percent ofall hydrosilylatable groups, and in order of increasing preference, lessthan 30 mol %, less than 20 mol %, less than 15 mol %, less than 10 mol%, and less than 5 mol %.

In general, the hydrosilylation reaction must occur in two steps, asindicated. The two separate hydrosilylations are important in assuringthat a majority of α-methylphenylethyl groups are bonded to residues ofthe M₄ ^(H)Q and/or M₃ ^(H)T^(phenyl) groups, as opposed to beingrandomly distributed. Moreover, the combined presence ofhydrosilylatable compounds comprising α-methylstyrene andhydrosilylatable organopolysiloxane containing at least twohydrosilylatable groups raises the possibility that extensivecrosslinking of the M₄ ^(H)Q and/or M₃ ^(H)T^(phenyl) groups with thehydrosilylatable organopolysiloxane can occur. Such products are likelyto be highly crosslinked solids. In either case, the product will not bethat claimed. However, it would not depart from the spirit of theinvention to include not more than 30 mol percent, preferably not morethan 20 mol percent and most preferably not more than 10 mol percent oftotal hydrosilylatable organopolysiloxane in the first step,particularly when α-methylstyrene alone or in substantial mol percent isto be used as the hydrosilylatable composition, and so long as a liquidproduct is obtained. Similarly, similar proportions of <30 mol %, <20mol %, and <10 mol percent of α-methylstyrene and/or long chain alkenerelative to the total amount of α-methylstyrene and long chain alkenemay be used in the second step. The goal is to produce products withchain-terminal and/or chain-pendent MQ and MT^(phenyl) groups, the Mgroups of which preferably contain at least two α-methylphenylethylgroups on average, preferably three α-methylphenylethyl groups in thecase of the MQ groups, and preferably two α-methylphenylethyl groups inthe case of MT groups.

Following the second stage hydrosilylation, the reaction mixture ispreferably devolatized under vacuum, and optionally stripped with theaid of a stripping gas such as dry nitrogen, to remove volatiles andunreacted low molecular weight starting materials or byproducts.

Examples of preparation of suitable silicone defoamer molecules arepresented in FIGS. 1-3.

In FIG. 1, the M₄ ^(H)Q organopolysiloxane has been reacted with threeequivalents of α-methylstyrene, and then used to hydrosilylate anα,ω-divinyl polydimethylsiloxane. The result is a simple A-B-Astructure.

In FIG. 2, again, 3 equivalents of α-methylstyrene are used, but thehydrosilylatable organopolysiloxane used has a functionality >2, andthus a branched structure is obtained.

In FIG. 3, less than 3 equivalents of α-methylstyrene, in conjunctionwith a hydrosilylatable organopolysiloxane with a functionality ofgreater than two, results in a three dimensional multibranched andpossibly crosslinked, although still liquid, product. The threedimensional nature of the products of FIGS. 2 and 3 cannot berealistically conveyed in two dimensions, and the “elipse” representsthe residue of the hydrosilylatable organopolysiloxane to which furtherM^(H)Q or M^(H)T^(phenyl) groups are bonded by hydrosilylation.

The defoamer compositions of the present invention also contain asilicone resin. The silicone resin may be an MQ resin, an MT resin, anMQT resin, or a T resin. The resin may also include D groups in amountsof less than 20 mol percent of all siloxy groups. As is well known,silicone resins are highly crosslinked, three dimensional, network-likepolymers. The silicone resins are solid at room temperature. Themeanings of M, D, T, and Q units are well known in silicone resinchemistry, and refer to, in the case of M, D, and T units,organo-substituted siloxy groups with 1, 2, and 3 siloxy bonds,respectively, and thus, 3, 2, and 1 organo groups, respectively. The Qgroup is the tetravalent SiO_(4/2) group. Preferred resins are MQresins. These resins are commercially available from numerous sources. Apreferred MQ resin is MQ 803, a product of Wacker Chemie, having acontent of about 40 mol % (CH₃)₃SiO_(1/2) (M) units, 50 mol % SiO_(4/2)(Q) units, 8 mol % C₂H₅OSiO_(3/2) (T) units, and about 2 mol %uncondensed HOSiO_(3/2) (T) units, with a weight average molecularweight of about 7900 g/mol, relative to polystyrene standard.Preferably, the silicone resins contain no Si—C or Si—O—C bondedpolyoxyalkylene groups.

The organo groups of the silicone resins may vary, but are generallylower C₁₋₄ alkyl or phenyl, preferably methyl. Some long chain C₅₋₁₈alkyl groups may also be present. Lower C₁₋₄ alkoxy groups are usuallypresent in a minor amount, and Si—OH groups (silanol functionality) areusually present in minor amount as well. The molecular weight M_(w) mayrange from 500 to 100,000 Da, more preferably 1000 to 40,000 Da, andmost preferably 2000 to 20,000 Da. More than one type of silicone resinmay be used.

A third constituent of the inventive defoamer compositions is silica.The silica may be colloidal silica or fumed (pyrogenic) silica,preferably fumed silica, and may have a BET surface area of, forexample, 30 m²/g to 400 m²/g, preferably 50 m²/g to 400 m²/g, and morepreferably 100 m²/g to 350 m²/g. The silica may be at least partlyhydrophobicized, or may be untreated. Untreated hydrophilic silica ispreferred. Such silicas, both partially surface modified (partiallyhydrophobicized) and untreated (hydrophilic), are commercially availablefrom numerous sources in a wide variety of BET surface areas. Aparticularly preferred silica is HDK® T30, a hydrophilic fumed silicawith a BET surface area of about 300 m²/g, available from Wacker ChemieAG, Munich, Germany.

The defoaming compositions of the subject invention may optionallycontain other ingredients as well. Especially preferred additionalingredients include other defoamers, such as paraffinic oils, lowmolecular weight polyolefin wax dispersions, long chain alcohols andtheir esters; fatty acids; silicone fluids, including bothtrimethylsilyl-terminated fluids and dimethylsilanol-terminated fluids;and further silicone resins, particularly low molecular weight liquidsilicone resins. This list is illustrative, and not limiting.

The defoaming compositions may be prepared by simple but intimate mixingor blending of components. Mixing may take place using conventionalstirrers and agitators, for example paddle stirrers, vane stirrers,rotor/stator mixers, impingement mixers, dissolvers, and the like.Preferably, the solid silicone resin is supplied to the mixing apparatusdissolved in a suitable solvent, which may remain in the product orwhich may subsequently be removed. Suitable solvents include: aromaticsolvents and aromatic solvent blends, containing, e.g. toluenes andxylenes, paraffinic hydrocarbons, ketones, ester solvents such as ethylacetate and t-butylacetate, long chain alkanols, and organopolysiloxanefluids such as trimethylsilyl-terminated polydimethyl siloxanes.Preferred solvents are those which may also exert some defoamingactivity, such as higher molecular weight aliphatic hydrocarbons, forexample, fractions having boiling points in the range of 70° C. to 350°C., more preferably 100° C. to 300° C., and most preferably 200° C. to300° C.

The inventive defoaming compositions are preferably used in liquid orsolid laundry and machine dishwashing detergent formulations, and theinvention thus further pertains to such formulations which include theinventive defoamers. Such formulations contain at least one surfactant,which may be, for example, anionic, cationic, amphoteric, zwitterionic,or non-ionic. The formulations may also include builders, sequestrants,anti-redeposition agents, alkalizing agents, bulking agents, fillers,fragrances, and the like. Such formulations are well known to thoseskilled in the art.

Examples Synthesis of Silicone Fluids

General Synthetic Procedure:

A four-necked round-bottomed flask, equipped with various neck adaptersand stopcock-equipped bypass adapter, to accommodate a mechanicalstirrer, thermocouple, addition funnel, water condenser, nitrogen gasinlet and outlet, and rubber septum, was used for the hydrosilation. Aheating mantle was used for heating the flask. An electronic thermostatwas used in conjunction with the thermocouple to control heating of theflask and contents. The preparation was conducted under a mild flow ofdry nitrogen gas. Upon completion of reaction, the water condenser wasby-passed or removed, and any volatiles were removed under vacuum. Theproduct was cooled to below 40° C. and filtered under air or nitrogenpressure using a 0.45-10 μm nylon or polyester membrane filter with orwithout a pre-filter. The reactions are highly exothermic and must becontrolled by adjusting the temperature and/or reagent addition rate.

Synthesis of Fluid I:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [130.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 136.1 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in cyclohexanol (1.02% Pt w/w inthe alcohol, 93 μL) was added quickly to the stirring (200-255 rpm)mixture in the flask via a syringe. A rapid exotherm ensued. AMSaddition from the funnel was continued to keep the temperature in therange of 140-160° C. from the heat of reaction. Upon completion of AMSaddition, the mixture was heated at 145° C. for 60 minutes. Vinylsilicone of approximate formula M^(Vi)D_(x)M^(Vi) (390.7 g, 2.66% w/wvinyl content) was added slowly from the addition funnel. Immediatelyafter the start of the silicone addition, a further aliquot of Ptcatalyst solution (93 μL) was added. After the vinyl silicone additionwas complete, the mixture was heated for 60 minutes at 155° C. withincreased mixing speed (approximately 425 rpm). The reaction mixture wasthen stripped under vacuum (5-15 mm Hg) at about 155° C. for 30 minutesto remove any residual volatiles. The product was then filtered aftercooling to yield an almost colorless transparent liquid. ¹H NMR analysisshowed the expected product. Viscosity: 154 mPa·s.

Synthesis of Fluid II:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane, TDSS[8.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 7.0 g) was charged to the addition funnel, andapproximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in cyclohexanol (1.02% Pt w/w inthe alcohol, 6 μL) was added quickly to the stirring (200-255 rpm)mixture in the flask via a syringe. A rapid exotherm ensued. AMSaddition from the funnel was continued to keep the temperature in therange of 140-160° C. from the heat of reaction. Upon completion of AMSaddition, the mixture was heated at 145° C. for 30 minutes.

Vinyl silicone of approximate formula M^(Vi)D_(x)M^(Vi) (310.9 g, 0.309%w/w vinyl content) was added slowly from the addition funnel.Immediately after the start of the silicone addition, a further aliquotof Pt catalyst solution (6 μL) was added. After the vinyl siliconeaddition was complete, another aliquot of the Pt catalyst solution (6μL) was added, and the mixture was heated for 60 minutes at 145° C. withincreased mixing speed (approximately 450 rpm). The reaction mixture wasthen stripped under vacuum (5-15 mm Hg) at approximately 155° C. for 30minutes to remove any residual volatiles. The thick liquid was thenfiltered after cooling to yield an almost colorless transparent thickliquid. ¹H NMR analysis showed the expected product. Viscosity: 93,844mPa·s.

Synthesis of Fluid III:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 78.5 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to about 100° C., and asolution of chloroplatinic acid in cyclohexanol (1% Pt w/w in thealcohol, 54 μL) was added quickly to the stirring (200-255 rpm) mixturein the flask via a syringe. A rapid exotherm ensued. AMS addition fromthe funnel was continued to keep the temperature in the range of140-165° C. from the heat of reaction. Another 81 μL of catalyst wasadded. Upon completion of AMS addition, the mixture was heated at 145°C. for 45 minutes. Silicone resin of approximate formulaM_(a)D_(b)T_(c)T^(Ph) _(d)D^(Vi) _(e) (M_(0.19)D_(0.13)T_(0.14)T^(PH)_(0.36)D^(Vi)0.18), where the M, D, and T units are methyl-substituted(122.5 g, 4.901% w/w vinyl content) was added slowly from the additionfunnel. Immediately after the start of the resin addition, an aliquot ofPt catalyst (54 μL) was added. After the resin addition was complete,another aliquot of Pt catalyst (54 μL) was added, and the mixture washeated for 60 minutes at 145° C. The reaction mixture was then strippedunder vacuum (5-15 mm Hg) at about 155° C. for 30 minutes to remove anyresidual volatiles. The brownish product was then filtered after coolingto yield a dark amber colored transparent liquid. ¹H NMR analysis showedthe expected product. Viscosity: 1569 mPa·s.

Synthesis of Fluid IV:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 73.3 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in dipropyleneglycol monobutylether (0.52% Pt w/w in the ether, 109 μL) was added quickly to thestirring (200-255 rpm) mixture in the flask via a syringe. A rapidexotherm ensued. AMS addition from the funnel was continued to keep thetemperature in the range of 140-165° C. from the heat of reaction. Uponcompletion of AMS addition, the mixture was heated at 145° C. for 30minutes. Silicone resin of approximate formula M_(a)D_(b)T_(c)T^(Ph)_(d)D^(Vi) _(e) (147.0 g, 4.901% w/w vinyl content) was added slowlyfrom the addition funnel. Immediately after the start of the resinaddition, an aliquot of Pt catalyst solution (109 μL) was added. Afterthe resin addition was complete, another aliquot of Pt catalyst solution(54 μL) was added, and the mixture was heated for 60 minutes at 155° C.with increased mixing speed (approximately 300 rpm). The reactionmixture was then stripped under vacuum (5-15 mm Hg) at about 155° C. for30 minutes to remove any residual volatiles. The dark amber coloredproduct was then filtered after cooling to yield a dark amber coloredtransparent liquid. ¹H NMR analysis showed the expected product.Viscosity: 8300 mPa·s.

Synthesis of Fluid V:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 72.0 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in dipropyleneglycol monobutylether (0.52% Pt w/w in the ether, 109 μL) was added quickly to thestirring (200-255 rpm) mixture in the flask via a syringe. A rapidexotherm ensued. AMS addition from the funnel was continued to keep thetemperature in the range of 140-165° C. from the heat of reaction. Uponcompletion of AMS addition, the mixture was heated at 145° C. for 30minutes. Silicone resin of approximate formula M_(a)D_(b)T_(c)T^(Ph)_(d)D^(Vi) _(e) (153.2 g, 4.901% w/w vinyl content) was added slowlyfrom the addition funnel. Immediately after the start of the resinaddition, an aliquot of Pt catalyst solution (109 μL) was added. Afterthe resin addition was complete, the mixture was heated for 60 minutesat 150° C. with increased mixing speed (approximately 425 rpm). Thereaction mixture was then stripped under vacuum (5-25 mm Hg) at about150° C. for 30 minutes to remove any residual volatiles. The dark ambercolored product was then filtered after cooling to yield a dark ambercolored transparent liquid. ¹H NMR analysis showed the expected product.Viscosity: 16,111 mPa·s.

Synthesis of Fluid VI:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 77.2 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in dipropyleneglycol monobutylether (0.52% Pt w/w in the ether, 109 μL) was added quickly to thestirring (200-255 rpm) mixture in the flask via a syringe. A rapidexotherm ensued. AMS addition from the funnel was continued to keep thetemperature in the range of 140-160° C. from the heat of reaction. Uponcompletion of AMS addition, the mixture was heated at 145° C. for 30minutes. Silicone resin of approximate formula M_(a)D_(b)T_(c)T^(Ph)_(a)D^(Vi) _(e) (128.6 g, 4.901% w/w vinyl content) was added slowlyfrom the addition funnel. Immediately after the start of the resinaddition, an aliquot of Pt catalyst solution (109 μL) was added. Afterthe resin addition was complete, the mixture was heated for 60 minutesat 150° C. with increased mixing speed (approximately 400 rpm). Thereaction mixture was then stripped under vacuum (5-25 mm Hg) at about155° C. for 30 minutes to remove any residual volatiles. The dark ambercolored product was then filtered after cooling to yield a dark ambercolored transparent liquid. ¹H NMR analysis showed the expected product.Viscosity: 2085 mPa·s.

Synthesis of Fluid VII:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 75.9 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in dipropyleneglycol monobutylether (0.52% Pt w/w in the ether, 109 μL) was added quickly to thestirring (200-255 rpm) mixture in the flask via a syringe. A rapidexotherm ensued. AMS addition from the funnel was continued to keep thetemperature in the range of 140-160° C. from the heat of reaction. Uponcompletion of AMS addition, the mixture was heated at 145° C. for 30minutes. Silicone resin of approximate formula M_(a)D_(b)T_(c)T^(Ph)_(d)D^(Vi) _(e) (134.8 g, 4.901% w/w vinyl content) was added slowlyfrom the addition funnel. Immediately after the start of the resinaddition, an aliquot of Pt catalyst solution (109 μL) was added. Afterthe resin addition was complete, the mixture was heated for 60 minutesat 150° C. with increased mixing speed (approximately 400 rpm). Thereaction mixture was then stripped under vacuum (5-25 mm Hg) at about155° C. for 30 minutes to remove any residual volatiles. The dark ambercolored product was then filtered after cooling to yield a dark ambercolored transparent liquid. ¹H NMR analysis showed the expected product.Viscosity: 2909 mPa·s.

Synthesis of Fluid VIII:

The reaction flask was charged with tetrakis(dimethylsiloxy)silane,TDSS, [75.0 g, 1.20% w/w H content]. The flask was heated to 80° C.,alpha-methylstyrene (AMS, 74.6 g) was charged to the addition funnel,and approximately one-sixth of the AMS was added to the flask. Thetemperature of the flask contents was raised to approximately 100° C.,and a solution of chloroplatinic acid in dipropyleneglycol monobutylether (0.52% Pt w/w in the ether, 109 μL) was added quickly to thestirring (200-255 rpm) mixture in the flask via a syringe. A rapidexotherm ensued. AMS addition from the funnel was continued to keep thetemperature in the range of 140-160° C. from the heat of reaction. Uponcompletion of AMS addition, the mixture was heated at 145° C. for 30minutes. Silicone resin of approximate formula M_(a)D_(b)T_(c)T^(Ph)_(d)D^(Vi) _(e) (140.9 g, 4.901% w/w vinyl content) was added slowlyfrom the addition funnel. Immediately after the start of the resinaddition, an aliquot of Pt catalyst solution (109 μL) was added. Afterthe resin addition was complete, the mixture was heated for 60 minutesat 150° C. with increased mixing speed (approximately 325 rpm). Thereaction mixture was then stripped under vacuum (5-25 mm Hg) at about155° C. for 30 minutes to remove any residual volatiles. The dark ambercolored product was then filtered after cooling to yield a dark ambercolored transparent liquid. ¹H NMR analysis showed the expected product.Viscosity: 3587 mPa·s.

Preparation of Defoamer Compounds:

Materials:

Silicone oil: AK 8000: A polydimethylsiloxane terminated withtrimethylsiloxane groups and having a viscosity of 0.008 m²/s.

Fluids I-VIII: synthesized according to the procedures described above.

Defoamer oil: a blend of silicone resin MQ 803 and Exxsol D 100 ULA.Exxsol D 100 ULA is a hydrocarbon mixture having a boiling range of210-280° C. obtained from ExxonMobil. Silicone resin MQ 803 is solid atroom temperature and is composed (by ²⁹Si NMR and IR analysis) of 40 mol% (CH₃)₃SiO_(1/2), 50 mol % SiO_(4/2), 8 mol % C₂H₅OSiO_(3/2), and 2 mol% HOSiO_(3/2) units, with a weight-average molar mass of 7900 g/mol(with reference to polystyrene standard).

Methanolic Potassium Hydroxide (20% Solution)

Filler: HDK T 30: a hydrophilic fumed silica having a surface area of300 m²/g, obtainable from Wacker Chemie AG Munich.

Method:

The silicone fluid (silicone oil AK 8000 for comparative example C1 oreither of the fluids I-VIII for inventive examples 1-8 below in Table1), defoamer and the methanolic potassium hydroxide solution wereweighed together in a 250 mL beaker and mixed briefly with a spatula.The filler HDK was added and mixed again until all of the HDK blended into form a homogeneous mixture. The mixture was mixed immediately for 10minutes with a dissolver at 800 rpm. After that, the mixture was heatedin a drying oven at 150° C. for 4 h, cooled down to room temperature andmixed with the dissolver for another 2 min at 800 rpm.

TABLE 1 Composition of defoamer compounds: % Example C1 Component (Comp.Example) Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Ex. 7 Ex. 8 A Silicone Oil87.39  — — — — — — — — AK 8000 Fluid I — 87.39  — — — — — — — Fluid II —— 87.39  — — — — — — Fluid III — — — 87.39  — — — — — Fluid IV — — — —87.39  — — — — Fluid V — — — — — 87.39  — — — Fluid VI — — — — — —87.39  — — Fluid VII — — — — — — — 87.39  — Fluid VIII — — — — — — — —87.39 B Defoamer Oil 5.91 5.91 5.91 5.91 5.91 5.91 5.91 5.91 5.91 CMethanolic KOH 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 (20%concentration) D HDK T 30 5.96 5.96 5.96 5.96 5.96 5.96 5.96 5.96 5.96

Viscosities of the Defoamer Compounds:

Viscosity (mPa · s) Ex C1 37,920 Ex. 1 1620 Ex. 2 500,000 Ex. 3 8720 Ex.4 60,500 Ex. 5 155,000 Ex. 6 13,200 Ex. 7 16,200 Ex. 8 19,700

Tests of Defoamer Effectiveness:

1. Antifoam Index AFI

In an apparatus in accordance with DE-A 25 51 260, 200 ml of a 4%strength by weight aqueous solution of a sodium alkylsulfonate(Mersolat™) containing 10 mg of the defoamer under investigation (insolution in 10 times the amount of methyl ethyl ketone) are foamed for 1minute using two counterrotating stirrers. Subsequently, the collapse ofthe foam is recorded. The area of the plot of foam height versus time isused to calculate the antifoam index (Table 2). The lower this index,the more effective is the defoamer.

TABLE 2 Antifoam index of defoamer compositions: Antifoam Example IndexEx C1 234 (comparative example) Ex. 1 657 Ex. 2 590 Ex. 3 165 Ex. 4 267Ex. 5 392 Ex. 6 110 Ex. 7 130 Ex. 8 157

2. Washing Machine Test Using a Powder Detergent

Antifoam powders were prepared by mixing the antifoam compounds(prepared according to the comparative example C1 and the inventiveexamples 1-8) according to the following composition:

Component Weight % Amount (g) Antifoam compounds (either 15.0 22.50 fromexamples C1 and 1-8) Pergopak M (polymethyl 5.0 7.50 urea resin withapprox. 0.6% reactive methylol groups; obtained from AlbemarleCorporation) Sodium sulphate 40.0 60.0 Sodiumhydrogencarbonate 40.0 60.0

The resulting mixtures were free flowing powders.

For evaluation of the defoamer powders prepared as above, the powderswere added to 130 g of a defoamer-free washing powder (TWM ECE-2 fromwfk-Testgewebe Gmbh, Germany) at different weight percentage levels (seeTable 3). The washing powder was then introduced together with 3500 g ofclean cotton laundry into a drum-type washing machine (Miele NovotronicW918 without Fuzzy Logic). Subsequently, the wash program was started(temperature: 40° C., water hardness: 3° dH), and the foam profile wasanalyzed with a ContiWashCam foam measurement system over a period of 55minutes. The system takes a picture of the foam level at the center ofthe washing machine window every minute. All pictures are compared witha reference picture. The automated program detects the foam level andcalculates it into percentage foam height. The wash cycle is dividedinto three segments and the average foam heights are calculated asaverage of the three wash cycles and are reported. The lower the averagepercentage, the more effective is the defoamer over the period as awhole.

The test results for powder defoamer are summarized below in TABLE 3:

TABLE 3 Washing machine test results for powder detergents % activedosage of Foam height defoamer compound during wash Example in thedetergent cycle % Ex C1 (comparative example) 0.13 56 Ex. 1 0.13 71 Ex.2 0.13 91 Ex. 3 0.13 2 Ex. 4 0.0325 22 Ex. 5 0.0325 44

According to the test results, Examples 3, 4 and 5 showed betterdefoaming performance in powder detergents (as evidenced by the % foamheights in the wash cycles) in the washing machine compared to thecomparative example C1. Examples 4 and 5 showed this improvedperformance even at much lower dosage level relative to the comparison.

3. Washing Machine Test Using a Liquid Detergent:

Defoamer compounds were added to 60 g of the defoamer-free liquiddetergent LD886 at different weight percentage levels (see Table 4). Theliquid detergent LD886 has the following composition:

Component Weight % Deionized water 65.1 Isotridecylalcohol 16.9Sodiumdoceylbenzenesulphonate 5.7 Sodiumlaurylsulphate 5.71.2-propanediol 5.6 Trisodiumcitrate-2-hydrate 1.0

The liquid detergents containing the defoamers were then introducedtogether with 3500 g of clean cotton laundry into a drum-type washingmachine (Miele Novotronic W918 without Fuzzy Logic). Subsequently thewash program was started (temperature: 40° C., water hardness: 3° dH),and the foam profile was analyzed with a ContiWashCam foam measurementsystem over a period of 55 minutes. The system takes a picture of thefoam level at the center of the washing machine window every minute. Allpictures are compared with a reference picture. The automated programdetects the foam level and calculates it into percentage foam height.The wash cycle is divided into three segments and the average foamheights are calculated as average of the three wash cycles and arereported. The lower the average percentage, the more effective is thedefoamer over the period as a whole.

TABLE 4 Results for liquid detergents % active dosage of defoamer Foamheight Example compound in the detergent during wash cycle % Ex. C1 0.313 (comparative example) Ex. 3 0.075 2 Ex. 6 0.075 8 Ex. 7 0.075 24 Ex.8 0.075 13

According to the test results, examples 3, 6, 7 and 8 showed similar orbetter defoaming performance in the liquid detergent formulations (asevidenced by the % foam heights in the wash cycles) in the washingmachine even at lower dosage level compared to the comparative exampleC1.

It should be noted that while some inventive defoamer compositionsperformed worse than the comparative example, performance is highlydependent upon the nature of the liquid being defoamed, e.g. content andtype of surfactants and other components, etc., and may be significantlybetter than the comparative example in other formulations, or in otherapplications previously mentioned.

While exemplary embodiments are described above, it is not intended thatthese embodiments describe all possible forms of the invention. Rather,the words used in the specification are words of description rather thanlimitation, and it is understood that various changes may be madewithout departing from the spirit and scope of the invention.Additionally, the features of various implementing embodiments may becombined to form further embodiments of the invention.

1. A defoamer composition, comprising: a) a liquid organopolysiloxaneprepared by a)i) in a first step, hydrosilylating an M₄ ^(H)Q siloxane,a M₃ ^(H)T^(phenyl) siloxane, or a mixture comprising an M₄ ^(H)Q and/orM₃ ^(H)T^(phenyl) siloxane wherein M₄ ^(H)Q siloxane has the structure[M^(H)-O]₄Si and M₃ ^(H)T^(phenyl) siloxane has the structure[M^(H)-O]₃Si-Φ where Φ is a phenyl group and M^(H) is a monovalentorganosilicon group of the formula H—Si(R¹ ₂)— where R¹ is a C₁₋₁₈ alkylor C₆ or C₁₀ aryl group, the aryl groups optionally substituted by oneor more C₁₋₁₈ alkyl groups, with a hydrosilylatable compositioncontaining at least 60 mol percent, based on total mols of thehydrosilylatable composition, of α-methylstyrene, to produce a firststage reaction product still containing Si—H bonded hydrogen; and a)ii)in a second step, hydrosilylating an organopolysiloxane bearing two ormore hydrosilylatable groups with the first stage reaction product toproduce a liquid organopolysiloxane; b) at least one silicone resin; andc) particulate silica.
 2. The defoamer composition of claim 1, whereinthe organopolysiloxane bearing two or more hydrosilylatable groups is avinyl-functional organopolysiloxane.
 3. The defoamer composition ofclaim 1, wherein the organopolysiloxane bearing two or morehydrosilylatable groups is an α,ω-dialkenyl-organopolysiloxane, anα,ω-dialkenyl-organopolysiloxane also containing at least one furtherchain-pendent Si—C bonded alkenyl group, an organopolysiloxane bearingonly chain-pendent alkenyl groups, or a mixture thereof.
 4. The defoamercomposition of claim 3, wherein the alkenyl groups are vinyl groups. 5.The defoamer composition of claim 1, wherein the hydrosilylatablecomposition of the first step consists of α-methylstyrene.
 6. Thedefoamer composition of claim 1, wherein the hydrosilylatablecomposition of the first step comprises α-methylstyrene and not morethan 40 mol percent, based on total mols of hydrosilylatable groups inthe hydrosilylatable composition, of a C₆₋₁₈ alkene.
 7. The defoamercomposition of claim 1, wherein the hydrosilylatable composition of thefirst step is present in an amount of from 1.8 to 3.2 mols ofhydrosilylatable groups per mol of M₄ ^(H)Q siloxane and 0.8 to 2.2 molsof hydrosilylatable groups per mol of M₃ ^(H)T^(phenyl) siloxane.
 8. Thedefoamer composition of claim 1, wherein the M₄ ^(H)Q siloxane comprisestetrakis(dimethylsiloxy)silane.
 9. The defoamer composition of claim 1,wherein at least one particulate silica is fumed silica having a BETsurface area of from 30 m²/g to 400 m²/g.
 10. A process for thepreparation of a defoamer composition of claim 1, comprising: mixing aliquid organopolysiloxane a) with silicone resin b) and particulatesilica c).
 11. The process of claim 10, wherein the silicone resin b) isfirst dissolved in a hydrocarbon(oxy) solvent prior to mixing withsilica c).
 12. The process of claim 11, wherein the hydrocarbon(oxy)solvent is a paraffinic hydrocarbon or mixture of paraffinichydrocarbons, boiling in the range of from 70° C. to 350° C.
 13. Theprocess of claim 10, further comprising adding a base to the mixture ofa), b), and c), and heating the resultant mixture.
 14. The process ofclaim 13, wherein the base comprises aqueous or alcoholic sodiumhydroxide or potassium hydroxide, or alcoholic sodium alkoxide orpotassium alkoxide.
 15. An organopolysiloxane, prepared by the processof: i) in a first step, hydrosilylating an M₄ ^(H)Q siloxane, a M₃^(H)T^(phenyl) siloxane, or a mixture comprising an M₄ ^(H)Q and/or M₃^(H)T^(phenyl) siloxane wherein M₄ ^(H)Q siloxane has the structure[M^(H)-O]₄Si and M₃ ^(H)T^(phenyl) siloxane has the structure[M^(H)-O]₃Si-Φ where Φ is a phenyl group and M^(H) is a monovalentorganosilicon group of the formula H—Si(R¹ ₂)— where R¹ is a C₁₋₁₈ alkylor C₆ or C₁₀ aryl group, the aryl groups optionally substituted by oneor more C₁₋₁₈ alkyl groups, with a hydrosilylatable compositioncontaining at least 60 mol percent, based on total mols of thehydrosilylatable composition, of α-methylstyrene, to produce a firststage reaction product still containing Si—H bonded hydrogen; and ii) ina second step, hydrosilylating an organopolysiloxane bearing two or morehydrosilylatable groups with the first stage reaction product to producea liquid organopolysiloxane.
 16. The organopolysiloxane of claim 15,wherein the organopolysiloxane bearing two or more hydrosilylatablegroups is a vinyl-functional organopolysiloxane.
 17. Theorganopolysiloxane of claim 15, wherein the hydrosilylatable compositionof the first step consists of α-methylstyrene.
 18. Theorganopolysiloxane of claim 15, wherein the hydrosilylatable compositionof the first step comprises α-methylstyrene and not more than 40 molpercent, based on total mols of hydrosilylatable groups in thehydrosilylatable composition, of a C₆₋₁₈ alkene.
 19. Theorganopolysiloxane of claim 15, wherein the hydrosilylatable compositionof the first step is present in an amount of from 1.8 to 3.2 mols ofhydrosilylatable groups per mol of M₄ ^(H)Q siloxane and 0.8 to 2.2 molsof hydrosilylatable groups per mol of M₃ ^(H)T^(phenyl) siloxane. 20.The organopolysiloxane of claim 15, wherein the M₄ ^(H)Q siloxanecomprises tetrakis(dimethylsiloxy)silane.
 21. In a detergent formulationemploying a defoamer composition, the improvement comprising includingat least one defoamer composition of claim 1 in the detergentformulation.